'A' value

Also contains definition of: Winstein–Holness A value
https://doi.org/10.1351/goldbook.A00012
The conformational preference of an @E02174@ compared to an axial substituent in a monosubstituted cyclohexane. This steric substituent parameter equals \(\Delta _{\text{r}}G^{\,\unicode{x26ac}}\) in \(\text{kcal mol}^{-1}\) for the @E02174@ to axial @E02175@ on cyclohexane. The values are also known as 'Winstein–Holness' A values.
Source:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1087 [Terms] [Paper]
Citation: ''A' value' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.A00012 RIS BibTex EndNote
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Last revised: February 24, 2014