non-Kekulé structure

https://doi.org/10.1351/goldbook.08190
Compound with unpaired electrons for which no Lewis structures are possible with all bonding electrons paired in single or double bonds.

Example 1:

Example 2:

Note: The isomer shown on the right (valence tautomer methylidenecyclopropane) is a Kekulé structure.

Source:
PAC, 2022, 94, 353. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 2021)) on page 472 [Terms] [Paper]