variational transition state theory

https://doi.org/10.1351/goldbook.V06603
This expression is applied to modifications of conventional @T06470@ in which the position of the @D01823@ in the potential-energy surface is varied. The rate is calculated with the surface at various positions, and the lowest rate calculated is taken to be closest to the truth.
Source:
PAC, 1996, 68, 149. (A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)) on page 190 [Terms] [Paper]
Citation: 'variational transition state theory' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.V06603 RIS BibTex EndNote
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Last revised: February 24, 2014