valence tautomerization

https://doi.org/10.1351/goldbook.V06591
The term describes simple reversible and generally rapid @I03295@ or @D01559@ involving the formation and rupture of single and/or double bonds, without @M03920@ of atoms or groups; e.g.
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See also:
fluxional
,
tautomerism
Source:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1175 [Terms] [Paper]
Citation: 'valence tautomerization' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.V06591 RIS BibTex EndNote
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Last revised: February 24, 2014