Potential energy gap between @R05163@ and the @T06468@, sometimes involving the zero point energies, but usually not.
See also:
critical energy
Sources: Green Book, 2nd ed., p. 56 [Terms] [Book] PAC, 1996, 68, 149. (A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)) on page 189 [Terms] [Paper]