temperature jump

https://doi.org/10.1351/goldbook.T06265
A @R05285@ technique in which the temperature of a chemical system is suddenly raised. The system then relaxes to a new state of equilibrium, and analysis of the @R05285@ processes provides rate constants.
See also:
relaxation
Sources:
PAC, 1993, 65, 2291. (Nomenclature of kinetic methods of analysis (IUPAC Recommendations 1993)) on page 2297 [Terms] [Paper]
PAC, 1996, 68, 149. (A glossary of terms used in chemical kinetics, including reaction dynamics (IUPAC Recommendations 1996)) on page 189 [Terms] [Paper]
Citation: 'temperature jump' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.T06265 RIS BibTex EndNote
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Last revised: February 24, 2014