polytopal rearrangement

https://doi.org/10.1351/goldbook.P04755
Stereoisomerization interconverting different or equivalent spatial arrangements of @L03518@ about a @C00930@ or of a @C00769@ of atoms, where the ligand or @C00769@ defines the vertices of a polyhedron. For example @P04956@ of @A00274@, @P04934@ of PF5, rearrangements of polyhedral @B00709@.
Source:
PAC, 1996, 68, 2193. (Basic terminology of stereochemistry (IUPAC Recommendations 1996)) on page 2213 [Terms] [Paper]
Citation: 'polytopal rearrangement' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.P04755 RIS BibTex EndNote
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Last revised: February 24, 2014