https://doi.org/10.1351/goldbook.P04608
A cell in which radiant energy causes a net chemical conversion in the cell, e.g. so as to produce hydrogen as a useful fuel. These cells can be classified as photosynthetic or photocatalytic. In the former case, radiant energy provides a Gibbs energy to drive a reaction such as \(\rm{H}_{2}\rm{O}\rightarrow \rm{H}_{2}+\frac{1}{2}\rm{O}_{2}\) , and electrical or thermal energy may be later recovered by allowing the reverse, spontaneous reaction to proceed. In a photocatalytic cell the photon absorption promotes a reaction with \(\Delta G < 0\) so there is no net storage of chemical energy, but the radiant energy speeds up a slow reaction.