intramolecular isotope effect

https://doi.org/10.1351/goldbook.I03132
A @K03405@ observed when a single substrate, in which the isotopic atoms occupy equivalent reactive positions, reacts to produce a non-statistical distribution of @I03352@ products. In such a case the @I03327@ will favour the pathway with lower @F02481@ for displacement of the isotopic nuclei in the @T06468@.
Source:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1130 [Terms] [Paper]
Citation: 'intramolecular isotope effect' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.I03132 RIS BibTex EndNote
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Last revised: February 24, 2014