Originally mixed acetals resulting from the attachment of a glycosyl group to a non-acyl group
RO– (which itself may be derived from a saccharide and chalcogen replacements thereof (
RS–,
RSe–).
G02661.png
The bond between the glycosyl group and the OR group is called a glycosidic bond. By extension, the terms
N-glycosides and
C-glycosides are used as class names for glycosylamines and for compounds having a glycosyl group attached to a hydrocarbyl group respectively.
G02661-2.png
These terms are misnomers and should not be used. The preferred terms are glycosylamines and
C-glycosyl compounds, respectively.
Sources:
PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1338 (https://doi.org/10.1351/pac199567081307)
White Book, 2nd ed., p. 136 (https://iupac.qmul.ac.uk/bibliog/white.html)