effective molarity (effective concentration)

https://doi.org/10.1351/goldbook.E01896
The ratio of the first-order @O04322@ of an @I03130@ reaction involving two functional groups within the same @M03986@ to the second-order @O04322@ of an analogous @I03098@ @E02035@. This ratio has the dimension of concentration. The term can also apply to an @E02177@.
See also:
intramolecular catalysis
Source:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1108 [Terms] [Paper]
Citation: 'effective molarity' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.E01896 RIS BibTex EndNote
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Last revised: February 24, 2014