captodative effect

https://doi.org/10.1351/goldbook.C00795
Effect on the stability of a carbon-centred @R05066@ determined by the combined action of a captor (electron withdrawing) and a dative (electron releasing) substituent, both attached to the radical centre. The term is also used for certain unsaturated compounds.
Source:
PAC, 1994, 66, 1077. (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1092 [Terms] [Paper]
Citation: 'captodative effect' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.C00795 RIS BibTex EndNote
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Last revised: February 24, 2014