molecular shuttle

https://doi.org/10.1351/goldbook.13971
Rotaxane or pseudorotaxane comprising a threading component upon which is threaded a macrocyclic component that, depending on the conditions, can reside at either a specific recognition site on the threading component or away from any recognition site.
molecular shuttle
molecular shuttle
Note: Rotaxane polymers composed of molecules that contain units of the molecular shuttle type are a special class of functional polymers.
Source:
PAC, 2012, 84, 2135. (Terminology and nomenclature for macromolecular rotaxanes and pseudorotaxanes (IUPAC Recommendations 2012)) on page 2139 [Terms] [Paper]