https://doi.org/10.1351/goldbook.12332
Desorption of molecules and formation of ions outside the mass spectrometer directly from samples in their native environment with no or minimal sample preparation.
Note: "Direct analysis in real time" is a proprietary term indicating the formation of ions from a solid or liquid sample at atmospheric pressure through the interaction of a gas stream containing internally excited atoms or molecules with the surface. The excited-state species are typically formed in a glow discharge in helium or nitrogen. The term should only be used to describe the commercial product.
Example: Desorption electrospray ionization (DESI) and direct analysis in real time (DART).