https://doi.org/10.1351/goldbook.10012
Estimate of a systematic examination error.
Example: 53 examined values were obtained with a reference examination procedure, 106 were obtained by Examination procedure 1 and with Examination procedure 2. Examination procedure 1 resulted in examined values with the same proportion distribution as for the Reference examination procedure, and the examined values have thus no examination bias. The 106 examined values with Examination procedure 2 have a different distribution compared to that of the reference nominal property values, and the examined values thus have an examination bias.
One estimate of examination bias for nominal properties is the Bhattacharyya distance, which measures the similarity of two nominal data sets. It equals zero when two proportion distributions are identical as is the case when comparing Examination procedure 1 and Reference examination procedure. There is an examination bias between Examination procedure 2 and Reference examination procedure, because the proportion distributions are different.
Possible examined values | Examined values | ||
Reference examination procedure | Examination procedure 1 | Examination procedure 2 | |
A | 21 | 42 | 2 |
B | 40 | ||
C | 18 | 36 | 2 |
D | 36 | ||
E | 12 | 24 | 10 |
F | 5 | ||
G | 2 | 4 | 11 |
Total number of examined values | 53 | 106 | 106 |
Notes:
- Examination bias is a quantity.
- If the proportion distributions of the reference nominal property values and the examined values are the same, there is no examination bias for the examining system. If the distributions differ there is an examination bias.
- In some publications on analytical chemistry, "examination bias" is termed "lack of reliability", but this is not recommended here.