residual liquid junction (potential) error

in pH measurement
https://doi.org/10.1351/goldbook.R05313
Error arising from breakdown in the assumption that the @L03584@ potential remains constant when solution X is substituted for solution S in the operational cell.
Source:
PAC, 1985, 57, 531. (Definition of pH scales, standard reference values, measurement of pH and related terminology (Recommendations 1984)) on page 541 [Terms] [Paper]
Citation: 'residual liquid junction (potential) error' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.R05313 RIS BibTex EndNote
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Last revised: February 24, 2014