Title: phosphoranyl radicals Long Title: IUPAC Gold Book - phosphoranyl radicals DOI: 10.1351/goldbook.P04568 Status: current Definition A tetracoordinate phosphorus species which has nine valence-shell electrons $\ce{R4P^{.}}$. Related Term - valence: https://goldbook.iupac.org//terms/view/V06588 Source - PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1359 (https://doi.org/10.1351/pac199567081307) Other Outputs - html: https://goldbook.iupac.org/terms/view/P04568/html - json: https://goldbook.iupac.org/terms/view/P04568/json - xml: https://goldbook.iupac.org/terms/view/P04568/xml Citation: Citation: 'phosphoranyl radicals' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.P04568 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Collection: If you are interested in licensing the Gold Book for commercial use, please contact the IUPAC Executive Director at executivedirector@iupac.org . Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using. Accessed: 2026-05-06T18:16:20+00:00