McLafferty rearrangement

in mass spectrometry
https://doi.org/10.1351/goldbook.M03772
β-Cleavage with concomitant specific transfer of a γ-hydrogen atom in a six-membered @T06468@ in mono-unsaturated systems, irrespective of whether the @R05194@ is formulated by a radical or an ionic mechanism, and irrespective of the position of the charge.
Source:
Orange Book, 2nd ed., p. 207 [Terms] [Book]
Citation: 'McLafferty rearrangement' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.M03772 RIS BibTex EndNote
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Last revised: February 24, 2014