Haber–Weiss reaction

https://doi.org/10.1351/goldbook.HT06787
The Haber–Weiss cycle consists of the following two reactions:
H2O2 + OH·-->H2O + O2− + H+
and
H2O2 + O2−-->O2 + OH− + OH·
The second reaction achieved notoriety as a possible source of hydroxyl radicals. However, it has a negligible @O04322@. It is believed that iron(III) complexes can catalyse this reaction: first, Fe(III) is reduced by superoxide, followed by @O04362@ by dihydrogen peroxide.
See also:
Fenton reaction
Source:
PAC, 1997, 69, 1251. (Glossary of terms used in bioinorganic chemistry (IUPAC Recommendations 1997)) on page 1277 [Terms] [Paper]
Citation: 'Haber–Weiss reaction' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.HT06787 RIS BibTex EndNote
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Last revised: February 24, 2014