geminate pair

https://doi.org/10.1351/goldbook.G02602
Pair of molecular entities in close proximity in solution within a solvent cage and resulting from reaction (e.g. bond scission, electron transfer, group transfer) of a precursor that constitutes a single kinetic entity.
See also: ion pair, radical pair
Source:
PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1117 (https://doi.org/10.1351/pac199466051077)