A hypothetical linear chain molecule consisting of infinitely thin rectilinear segments uniform in length; each segment can take all orientations in space with equal probability, independently of its neighbours. For models in which the segments are not all uniform in length, the name 'random-walk chain' has been used.
Source:
Purple Book, 1st ed., p. 50 (http://old.iupac.org/publications/books/author/metanomski.html)