A high-frequency mass spectrometer in which the cyclotron motion of ions, having different mass/charge ratios, in a constant magnetic field is excited essentially simultaneously and coherently by a pulse or a radio-frequency electric field applied perpendicular to the magnetic field. The excited cyclotron motion of the ions is subsequently detected on so-called receiver plates as a time domain signal that contains all the cyclotron frequencies that have been excited. Fourier transformation of the time domain signal results in the frequency domain
FT-ICR signal which, on the basis of the inverse proportionality between frequency and the mass/charge ratio, can be converted into a mass spectrum. The term is sometimes contracted to Fourier transform mass spectrometer (
FT-MS).
See also: ion cyclotron resonance (ICR) mass spectrometer
Source:
PAC, 1991, 63, 1541. 'Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)' on page 1545 (https://doi.org/10.1351/pac199163101541)