Compounds formally derived from an oxoacid
RkE(=O)l(OH)m, (
l ≠ 0) and an alcohol, phenol, heteroarenol, or enol by linking with formal loss of water from an acidic hydroxy group of the former and a hydroxy group of the latter. By extension acyl derivatives of alcohols, etc. Acyl derivatives of chalcogen analogues of alcohols (thiols, selenols, tellurols) etc. are included. E.g.
R'C(=O)(OR),
R'C(=S)(OR),
R'C(=O)(SR),
R'S(=O)2(OR),
(HO)2P(=O)(OR),
(R'S)2C(=O),
ROCN (but not
R–NCO) (
R ≠
H).
Note:
O-Alkyl derivatives of other acidic compounds [see @A00266@] may be named as esters but do not belong to the class esters proper. E.g. (Ph)2POCH3 methyl diphenylphosphinite.
See also: acylals, ortho esters, depsides, depsipeptides, glycerides, lactides, lactones, macrolides
Source:
PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1334 (https://doi.org/10.1351/pac199567081307)