The process that occurs when the vapour pressure of the saturated aqueous solution of a substance is less than the vapour pressure of water in the ambient air. When water vapour is collected by the pure solid compound, a mixture of the solid and liquid or an aqueous solution of the compound forms until the substance is dissolved and is in equilibrium with its environment; at this time the vapour pressure of water over the aqueous solution will equal the @P04420@ of water in the atmosphere in contact with it. A crystalline @S05447@ @A00176@ particle will deliquesce in the atmosphere when the @R05267@ surpasses a characteristic value, the so-called deliquescence point.