dead-volume [obsolete]

in chromatography
https://doi.org/10.1351/goldbook.D01532
This term is used to express the @E02295@. Strictly speaking, the term 'dead-volume' refers to volumes within the chromatographic system which are not swept by the mobile phase. On the other hand, mobile phase is flowing through most of the extra-column volumes. Due to this ambiguity the use of term 'dead-volume' is discouraged.
Source:
PAC, 1993, 65, 819. (Nomenclature for chromatography (IUPAC Recommendations 1993)) on page 833 [Terms] [Paper]
See also:
Orange Book, 2nd ed., p. 101 [Terms] [Book]
Citation: 'dead-volume' in IUPAC Compendium of Chemical Terminology, 3rd ed. International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. https://doi.org/10.1351/goldbook.D01532 RIS BibTex EndNote
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Last revised: February 24, 2014