<?xml version="1.0" encoding="UTF-8"?>
<term>
  <id>01526</id>
  <title>Davydov splitting</title>
  <longtitle>IUPAC Gold Book - Davydov splitting</longtitle>
  <doi>10.1351/goldbook.D01526</doi>
  <code>D01526</code>
  <status>current</status>
  <synonym><em>synonym</em>: factor-group splitting</synonym>
  <definitions>
    <item>
      <id>1</id>
      <text>The splitting of bands in the electronic or vibrational spectra of crystals due to the presence of more than one (interacting) equivalent molecular entity in the unit cell.</text>
      <links>
        <item>
          <term>unit cell</term>
          <url>https://goldbook.iupac.org//terms/view/U06562</url>
        </item>
      </links>
      <sources>
        <item>PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2235 (https://doi.org/10.1351/pac199668122223)</item>
      </sources>
    </item>
  </definitions>
  <altoutputs>
    <html>https://goldbook.iupac.org/terms/view/D01526/html</html>
    <json>https://goldbook.iupac.org/terms/view/D01526/json</json>
    <plain>https://goldbook.iupac.org/terms/view/D01526/plain</plain>
  </altoutputs>
  <citation>Citation: 'Davydov splitting' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.D01526</citation>
  <license>The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms.</license>
  <collection>If you are interested in licensing the Gold Book for commercial use, please contact the IUPAC Executive Director at executivedirector@iupac.org .</collection>
  <disclaimer>The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.</disclaimer>
  <accessed>2026-07-16T04:23:05+00:00</accessed>
</term>
