Title: critical thickness of a film Long Title: IUPAC Gold Book - critical thickness of a film DOI: 10.1351/goldbook.C01403 Status: current Definition A film often thins gradually to a thickness at which it either ruptures or converts abruptly to an equilibrium film. This thickness is sometimes well enough defined statistically to be considered a critical thickness, \(t_{\rm{c}}\) or \(h_{\rm{c}}\). Related Terms - equilibrium film: https://goldbook.iupac.org//terms/view/E02181 - film: https://goldbook.iupac.org//terms/view/F02366 Source - PAC, 1972, 31, 577. 'Manual of Symbols and Terminology for Physicochemical Quantities and Units, Appendix II: Definitions, Terminology and Symbols in Colloid and Surface Chemistry' on page 614 (https://doi.org/10.1351/pac197231040577) Other Outputs - html: https://goldbook.iupac.org/terms/view/C01403/html - json: https://goldbook.iupac.org/terms/view/C01403/json - xml: https://goldbook.iupac.org/terms/view/C01403/xml Citation: Citation: 'critical thickness of a film' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.C01403 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Collection: If you are interested in licensing the Gold Book for commercial use, please contact the IUPAC Executive Director at executivedirector@iupac.org . Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using. Accessed: 2026-07-02T13:21:52+00:00