Title: critical excitation energy Long Title: IUPAC Gold Book - critical excitation energy DOI: 10.1351/goldbook.C01394 Status: current Index: quantity Definition Minimum energy to excite a specific analytical signal. The term is most frequently used in connection with the generation of X-ray spectra, designating the ionization (binding) energy of the orbital on which the transition ends. Related Term - ionization (binding) energy: https://goldbook.iupac.org//terms/view/I03199 Source - PAC, 1983, 55, 2023. 'Nomenclature, symbols and units recommended for in situ microanalysis (Provisional)' on page 2027 (https://doi.org/10.1351/pac198355122023) Other Outputs - html: https://goldbook.iupac.org/terms/view/C01394/html - json: https://goldbook.iupac.org/terms/view/C01394/json - xml: https://goldbook.iupac.org/terms/view/C01394/xml Citation: Citation: 'critical excitation energy' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.C01394 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Collection: If you are interested in licensing the Gold Book for commercial use, please contact the IUPAC Executive Director at executivedirector@iupac.org . Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using. Accessed: 2026-04-27T14:55:53+00:00