Generic name for anions containing an even number of electrons and having an unshared pair of electrons on a tervalent carbon atom (e.g.
Cl3C− or
HC≡C− ) or — if the ion is mesomeric (see mesomerism) — having at least one significant contributing structure with an unshared pair of electrons on a tervalent carbon atom, for example:
C00804-1.png
See also: radical ion
Source:
PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1092 (https://doi.org/10.1351/pac199466051077)
See also:
PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1324 (https://doi.org/10.1351/pac199567081307)