Title: self-initiated polymerisation Long Title: IUPAC Gold Book - self-initiated polymerisation DOI: 10.1351/goldbook.15420 Status: current Definition Polymerization in which initiating species are formed exclusively from the monomer. Source - PAC, 2008, 80, 2163. 'Glossary of terms related to kinetics, thermodynamics, and mechanisms of polymerization (IUPAC Recommendations 2008)' on page 2184 (https://doi.org/10.1351/pac200880102163) Other Outputs - html: https://goldbook.iupac.org/terms/view/15420/html - json: https://goldbook.iupac.org/terms/view/15420/json - xml: https://goldbook.iupac.org/terms/view/15420/xml Citation: Citation: 'self-initiated polymerisation' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.15420 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Collection: If you are interested in licensing the Gold Book for commercial use, please contact the IUPAC Executive Director at executivedirector@iupac.org . Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using. Accessed: 2026-04-18T06:46:23+00:00