degenerate-transfer radical polymerisation

initialism: DTRP
https://doi.org/10.1351/goldbook.14412
Controlled reversible-deactivation radical polymerization in which the deactivation of the radicals involves degenerative transfer (DT) of a group (or atom).
Examples: Those mentioned below under reversible-addition-fragmentation chain-transfer polymerisation, iodine (iodine transfer polymerisation, ITP) and certain derivatives of \(\ce{Te}\), \(\ce{As}\), \(\ce{Sb}\), or \(\ce{Bi}\).
Source:
PAC, 2009, 82, 483. (Terminology for reversible-deactivation radical polymerization previously called "controlled" radical or "living" radical polymerization (IUPAC Recommendations 2010)) on page 489 [Terms] [Paper]
Citation: 'degenerate-transfer radical polymerisation' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. https://doi.org/10.1351/goldbook.14412 RIS BibTex EndNote
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