<?xml version="1.0" encoding="UTF-8"?>
<term>
  <id>13977</id>
  <title>rotaxane end-unit</title>
  <longtitle>IUPAC Gold Book - rotaxane end-unit</longtitle>
  <doi>10.1351/goldbook.13977</doi>
  <code>13977</code>
  <status>current</status>
  <abbrev><em>abbrev</em>: <em>rot</em>-EU</abbrev>
  <definitions>
    <item>
      <id>1</id>
      <text>Constitutional unit of a macromolecular rotaxane consisting of an end-group of its macromolecular component and a complementary threading or macrocyclic component.</text>
      <notes>
        <item>End-group is a constitutional unit that is an extremity of a macromolecule or oligomer molecule. An end-group is attached to only one constitutional unit of a macromolecule or oligomer molecule.</item>
      </notes>
      <links>
        <item>
          <term>macrocyclic component</term>
          <url>https://goldbook.iupac.org//terms/view/13965</url>
        </item>
        <item>
          <term>macromolecular rotaxane</term>
          <url>https://goldbook.iupac.org//terms/view/13968</url>
        </item>
        <item>
          <term>threading</term>
          <url>https://goldbook.iupac.org//terms/view/13985</url>
        </item>
      </links>
      <sources>
        <item>PAC, 2012, 84, 2135. 'Terminology and nomenclature for macromolecular rotaxanes and pseudorotaxanes (IUPAC Recommendations 2012)' on page 2142 (https://doi.org/10.1351/PAC-REC-11-10-15)</item>
      </sources>
    </item>
  </definitions>
  <altoutputs>
    <html>https://goldbook.iupac.org/terms/view/13977/html</html>
    <json>https://goldbook.iupac.org/terms/view/13977/json</json>
    <plain>https://goldbook.iupac.org/terms/view/13977/plain</plain>
  </altoutputs>
  <citation>Citation: 'rotaxane end-unit' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.13977</citation>
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  <disclaimer>The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.</disclaimer>
  <accessed>2026-05-09T17:43:26+00:00</accessed>
</term>
