Title: layer-by-layer assembly Long Title: IUPAC Gold Book - layer-by-layer assembly DOI: 10.1351/goldbook.13835 Status: current Definition Process whereby multilayered structures of molecules or particles of a substance are assembled on a solid substrate by sequential adsorption of monolayers held together by noncovalent interactions. Notes 1) The material at the liquid surface need not necessarily be present as a solid monolayer. 2) Layer-by-layer assembly is often used to alternately transfer polyelectrolytes that are positively and negatively charged. Source - PAC, 2012, 85, 463. 'Terminology for aggregation and self-assembly in polymer science (IUPAC Recommendations 2013)' on page 476 (https://doi.org/10.1351/PAC-REC-12-03-12) Other Outputs - html: https://goldbook.iupac.org/terms/view/13835/html - json: https://goldbook.iupac.org/terms/view/13835/json - xml: https://goldbook.iupac.org/terms/view/13835/xml Citation: Citation: 'layer-by-layer assembly' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.13835 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Collection: If you are interested in licensing the Gold Book for commercial use, please contact the IUPAC Executive Director at executivedirector@iupac.org . Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using. Accessed: 2026-06-29T14:56:11+00:00