<?xml version="1.0" encoding="UTF-8"?>
<term>
  <id>12797</id>
  <title>reversing heat flow</title>
  <longtitle>IUPAC Gold Book - reversing heat flow</longtitle>
  <doi>10.1351/goldbook.12797</doi>
  <code>12797</code>
  <status>current</status>
  <definitions>
    <item>
      <id>1</id>
      <text>In modulated-temperature DSC the heat-capacity component of the total heat flow that is in-phase with the temperature modulation.</text>
      <notes>
        <item>The reversing-heat-flow component contains the changes in the heat capacity, \(C_{p}\), of the specimen, in particular during the glass transition.</item>
        <item>The term "reversing" must not be confused with "reversible".</item>
      </notes>
      <links>
        <item>
          <term>modulated-temperature DSC</term>
          <url>https://goldbook.iupac.org//terms/view/12790</url>
        </item>
      </links>
      <sources>
        <item>PAC, 2013, 85, 1017. 'Glossary of terms relating to thermal and thermomechanical properties of polymers (IUPAC Recommendations 2013)' on page 1037 (https://doi.org/10.1351/PAC-REC-12-03-02)</item>
      </sources>
    </item>
  </definitions>
  <altoutputs>
    <html>https://goldbook.iupac.org/terms/view/12797/html</html>
    <json>https://goldbook.iupac.org/terms/view/12797/json</json>
    <plain>https://goldbook.iupac.org/terms/view/12797/plain</plain>
  </altoutputs>
  <citation>Citation: 'reversing heat flow' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.12797</citation>
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  <disclaimer>The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.</disclaimer>
  <accessed>2026-07-13T10:26:15+00:00</accessed>
</term>
