reference ion

https://doi.org/10.1351/goldbook.12550
Stable ion whose structure or elemental formula is known with certainty. These ions are formed by direct ionization of a molecule of known structure or elemental formula, and are used to verify by comparison the structure or thermochemistry of an unknown ion or to calibrate the m/z scale of the mass spectrometer.
Source:
PAC, 2013, 85, 1515. (Definitions of terms relating to mass spectrometry (IUPAC Recommendations 2013)) on page 1584 [Terms] [Paper]