10197 IUPAC Gold Book - full-evaporation headspace analysis 10.1351/goldbook.10197 10197 current 1 Small volume of sample in a headspace vessel maintained at a temperature sufficient to cause complete evaporation of analytes. The full-evaporation technique is used with both static headspace analysis and dynamic headspace analysis. Equilibrium between the condensed and vapor phases no longer exists. As a consequence, the possibility of matrix interferences is reduced and the fraction extracted for low-volatility compounds is increased. PAC, 2016, 88, 517. 'Glossary of terms used in extraction (IUPAC Recommendations 2016)' on page 529 (https://doi.org/10.1515/pac-2015-0903) https://goldbook.iupac.org/terms/view/10197/html https://goldbook.iupac.org/terms/view/10197/json https://goldbook.iupac.org/terms/view/10197/plain Citation: 'full-evaporation headspace analysis' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.10197 The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. If you are interested in licensing the Gold Book for commercial use, please contact the IUPAC Executive Director at executivedirector@iupac.org . The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using. 2026-04-21T09:41:04+00:00