Title: spectator hole Long Title: IUPAC Gold Book - spectator hole DOI: 10.1351/goldbook.09356 Status: current Definition Electronic configuration of an atom containing an electronic vacancy that can be present during processes, such as Auger electron and X-ray photoelectron emission, but is not created or destroyed in the process. Related Term - X-ray photoelectron emission: https://goldbook.iupac.org//terms/view/09348 Source - PAC, 2020, 92, 1781. 'Glossary of methods and terms used in surface chemical analysis (IUPAC Recommendations 2020)' on page 1830 (https://doi.org/10.1515/pac-2019-0404) Other Outputs - html: https://goldbook.iupac.org/terms/view/09356/html - json: https://goldbook.iupac.org/terms/view/09356/json - xml: https://goldbook.iupac.org/terms/view/09356/xml Citation: Citation: 'spectator hole' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.09356 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Collection: If you are interested in licensing the Gold Book for commercial use, please contact the IUPAC Executive Director at executivedirector@iupac.org . Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using. Accessed: 2026-04-20T15:19:48+00:00