Title: total reflection X-ray fluorescence spectroscopy Long Title: IUPAC Gold Book - total reflection X-ray fluorescence spectroscopy DOI: 10.1351/goldbook.09211 Status: current Definition Measurement method in which an X-ray spectrometer is used to measure the energy distribution of fluorescence X-rays emitted from a surface irradiated by primary X-rays under the condition of total reflection. Related Term - total reflection: https://goldbook.iupac.org//terms/view/09440 Source - PAC, 2020, 92, 1781. 'Glossary of methods and terms used in surface chemical analysis (IUPAC Recommendations 2020)' on page 1794 (https://doi.org/10.1515/pac-2019-0404) Other Outputs - html: https://goldbook.iupac.org/terms/view/09211/html - json: https://goldbook.iupac.org/terms/view/09211/json - xml: https://goldbook.iupac.org/terms/view/09211/xml Citation: Citation: 'total reflection X-ray fluorescence spectroscopy' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.09211 License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. Collection: If you are interested in licensing the Gold Book for commercial use, please contact the IUPAC Executive Director at executivedirector@iupac.org . Disclaimer: The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using. Accessed: 2026-05-18T04:28:30+00:00