<?xml version="1.0" encoding="UTF-8"?>
<term>
  <id>09098</id>
  <title>solid amalgam electrode</title>
  <longtitle>IUPAC Gold Book - solid amalgam electrode</longtitle>
  <doi>10.1351/goldbook.09098</doi>
  <code>09098</code>
  <status>current</status>
  <initialism><em>initialism</em>: SAE</initialism>
  <definitions>
    <item>
      <id>1</id>
      <text>Electrode made of a solid amalgam of an appropriate metal.</text>
      <notes>
        <item>Solid amalgam electrodes are electrochemically similar to the hanging mercury drop electrode. Their main advantages are high hydrogen overpotential (similar to liquid mercury); a wide working potential range; the simple mechanical, chemical, and electrochemical regeneration of the surface; a long lifetime; low toxicity of material (comparable with that of dental amalgams); applicability for field measurements; compatibility with flow-through systems; simple construction, without mobile parts; and easy miniaturization.</item>
        <item>Liquid and paste amalgams can also be used.</item>
      </notes>
      <links>
        <item>
          <term>Electrode</term>
          <url>https://goldbook.iupac.org//terms/view/09060</url>
        </item>
        <item>
          <term>hanging mercury drop electrode</term>
          <url>https://goldbook.iupac.org//terms/view/09103</url>
        </item>
        <item>
          <term>working potential range</term>
          <url>https://goldbook.iupac.org//terms/view/09082</url>
        </item>
      </links>
      <sources>
        <item>PAC, 2020, 92, 641. 'Terminology of Electrochemical Methods of Analysis (IUPAC Recommendations 2019)' on page 659 (https://doi.org/10.1515/pac-2018-0109)</item>
      </sources>
    </item>
  </definitions>
  <altoutputs>
    <html>https://goldbook.iupac.org/terms/view/09098/html</html>
    <json>https://goldbook.iupac.org/terms/view/09098/json</json>
    <plain>https://goldbook.iupac.org/terms/view/09098/plain</plain>
  </altoutputs>
  <citation>Citation: 'solid amalgam electrode' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.09098</citation>
  <license>The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms.</license>
  <collection>If you are interested in licensing the Gold Book for commercial use, please contact the IUPAC Executive Director at executivedirector@iupac.org .</collection>
  <disclaimer>The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.</disclaimer>
  <accessed>2026-05-09T11:00:24+00:00</accessed>
</term>
