09008 IUPAC Gold Book - rare-earth-metal-mediated coordination-addition polymerization 10.1351/goldbook.09008 09008 current synonyms: lanthanide-mediated group-transfer polymerization, rare-earth-metal-mediated coordination polymerization, rare-earth-metal-mediated group-transfer polymerization 1 Coordination-addition polymerization with propagation occurring within the coordination sphere of a rare-earth metal complex. The process may also involve non-rare-earth metal complexes with a sufficiently large coordination sphere (e.g., zirconium). PAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1139 (https://doi.org/10.1515/pac-2020-1211) https://goldbook.iupac.org/terms/view/09008/html https://goldbook.iupac.org/terms/view/09008/json https://goldbook.iupac.org/terms/view/09008/plain Citation: 'rare-earth-metal-mediated coordination-addition polymerization' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.09008 The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. If you are interested in licensing the Gold Book for commercial use, please contact the IUPAC Executive Director at executivedirector@iupac.org . The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using. 2026-06-22T02:35:48+00:00