https://doi.org/10.1351/goldbook.09002
Coordination polymerization in which the chain carrier migrates along the formed polymer chain through a series of \(\ce{\upbeta {-}hydrogen}\) eliminations and reinsertions with inversion of stereochemistry.
Notes:
- In contrast to classical coordination polymerizations, which provide linear polyethylene, CWP of ethylene leads to a branched polymer.
- CWP of \(\ce{\upbeta {-}olefins}\) generally leads to less branched polymers than those formed by classical coordination polymerization.
Examples: Aryl-substituted α-diimine-palladium(II) complexes.