<?xml version="1.0" encoding="UTF-8"?>
<term>
  <id>08994</id>
  <title>electron-transfer ring-opening metathesis polymerization</title>
  <longtitle>IUPAC Gold Book - electron-transfer ring-opening metathesis polymerization</longtitle>
  <doi>10.1351/goldbook.08994</doi>
  <code>08994</code>
  <status>current</status>
  <acronym><em>acronym</em>: ET-ROMP</acronym>
  <definitions>
    <item>
      <id>1</id>
      <text>Ring-opening metathesis polymerization (ROMP) proceeding through one-electron redox processes in the absence of a metal carbene initiator.</text>
      <notes>
        <item>ET-ROMP may be initiated by single electron-transfer to a vinyl ether from a photoredox catalyst or by electrochemical processes to create a radical cation as the kinetic-chain carrier.</item>
      </notes>
      <links>
        <item>
          <term>Ring-opening metathesis polymerization</term>
          <url>https://goldbook.iupac.org//terms/view/08933</url>
        </item>
      </links>
      <sources>
        <item>PAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1134 (https://doi.org/10.1515/pac-2020-1211)</item>
      </sources>
    </item>
  </definitions>
  <altoutputs>
    <html>https://goldbook.iupac.org/terms/view/08994/html</html>
    <json>https://goldbook.iupac.org/terms/view/08994/json</json>
    <plain>https://goldbook.iupac.org/terms/view/08994/plain</plain>
  </altoutputs>
  <citation>Citation: 'electron-transfer ring-opening metathesis polymerization' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.08994</citation>
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  <disclaimer>The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.</disclaimer>
  <accessed>2026-04-18T05:52:36+00:00</accessed>
</term>
