<?xml version="1.0" encoding="UTF-8"?>
<term>
  <id>08940</id>
  <title>catalytic chain termination</title>
  <longtitle>IUPAC Gold Book - catalytic chain termination</longtitle>
  <doi>10.1351/goldbook.08940</doi>
  <code>08940</code>
  <status>current</status>
  <definitions>
    <item>
      <id>1</id>
      <text>Chain termination process involving transfer of a group to a reagent (the catalyst) that in turn transfers that group to a propagating species to terminate a chain and regenerate the original reagent.</text>
      <notes>
        <item>Catalytic chain termination may be observed as a side reaction in certain reversible-deactivation radical polymerizations.</item>
      </notes>
      <links>
        <item>
          <term>propagating species</term>
          <url>https://goldbook.iupac.org//terms/view/08966</url>
        </item>
        <item>
          <term>reversible-deactivation radical polymerizations</term>
          <url>https://goldbook.iupac.org//terms/view/08916</url>
        </item>
      </links>
      <sources>
        <item>PAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1116 (https://doi.org/10.1515/pac-2020-1211)</item>
      </sources>
    </item>
  </definitions>
  <altoutputs>
    <html>https://goldbook.iupac.org/terms/view/08940/html</html>
    <json>https://goldbook.iupac.org/terms/view/08940/json</json>
    <plain>https://goldbook.iupac.org/terms/view/08940/plain</plain>
  </altoutputs>
  <citation>Citation: 'catalytic chain termination' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.08940</citation>
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  <collection>If you are interested in licensing the Gold Book for commercial use, please contact the IUPAC Executive Director at executivedirector@iupac.org .</collection>
  <disclaimer>The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using.</disclaimer>
  <accessed>2026-05-08T11:35:24+00:00</accessed>
</term>
