cobalt-mediated radical polymerization

initialism: CMRP

https://doi.org/10.1351/goldbook.08918

Reversible-deactivation radical polymerization mediated by a cobalt complex.

Note: The mechanism of cobalt-mediated radical polymerization may involve stable-radical-mediated polymerization (SRMP), degenerative chain-transfer radical polymerization, (DTRP), atom-transfer radical polymerization (ATRP) or some combination of these depending on the specific reagents and reaction conditions.

See also: organometallic-mediated radical polymerization

Source:
PAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1106 (https://doi.org/10.1515/pac-2020-1211)