08398 IUPAC Gold Book - pure shift yielded by chirp excitation 10.1351/goldbook.08398 08398 current acronym: PSYCHE 1 Nuclear magnetic resonance spectroscopy experiment generating homonuclear spin-spin decoupled spectra. The effect is achieved through the concatenation of partial free induction decays generated with a series of swept adiabatic pulses. \(\ce{^{1}H}\) spectrum with no \(\ce{^{1}H},\ce{^{1}H}\) coupling. Nuclear magnetic resonance spectroscopy https://goldbook.iupac.org//terms/view/08218 free induction decays https://goldbook.iupac.org//terms/view/08249 spectrum https://goldbook.iupac.org//terms/view/08384 PAC, 2021, 93, 647. 'Glossary of methods and terms used in analytical spectroscopy (IUPAC Recommendations 2019)' on page 701 (https://doi.org/10.1515/pac-2019-0203) https://goldbook.iupac.org/terms/view/08398/html https://goldbook.iupac.org/terms/view/08398/json https://goldbook.iupac.org/terms/view/08398/plain Citation: 'pure shift yielded by chirp excitation' in IUPAC Compendium of Chemical Terminology, 5th ed. International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.08398 The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International (https://creativecommons.org/licenses/by-sa/4.0/) for individual terms. If you are interested in licensing the Gold Book for commercial use, please contact the IUPAC Executive Director at executivedirector@iupac.org . The International Union of Pure and Applied Chemistry (IUPAC) is continuously reviewing and, where needed, updating terms in the Compendium of Chemical Terminology (the IUPAC Gold Book). Users of these terms are encouraged to include the version of a term with its use and to check regularly for updates to term definitions that you are using. 2026-04-17T21:29:34+00:00