commutability of a reference material

https://doi.org/10.1351/goldbook.08064
Property of a reference material, demonstrated by the closeness of agreement between the relation among the measurement results for a stated quantity in this material, obtained according to two given measurement procedures, and the relation obtained among the measurement results for other specified materials.
Notes:
  1. The reference material in question is usually a calibrator and the other specified materials are usually routine samples.
  2. The measurement procedures referred to in the definition are the one preceding and the one following the reference material (calibrator) in question in a calibration hierarchy (see ISO 17511).
  3. The material stability of commutable reference materials should be monitored regularly.
  4. Cases in which a reference material producer is required to conduct assessment of commutability are outlined in ISO 15194.
  5. Guidance for assessment of commutability of reference material in laboratory medicine is provided by IFCC.
Source:
PAC, 2021, 93, 997. (Metrological and quality concepts in analytical chemistry (IUPAC Recommendations 2021)) on page 1022 [Terms] [Paper]